Bernalillo County Sheriff's officials say the victim is 67-year-old Thomas Fosbre.
They say his car was struck from behind about 7:30 p.m. Friday by a vehicle driven by a 60-year-old Arroyo Seco woman.
Authorities say Fosbre's car left the roadway and rolled. He was pronounced deceased on scene.
Sheriff's officials say the driver of the other vehicle smelled of alcohol and was booked into jail on suspicion of driving under the influence resulting in vehicular homicide.
They say the woman's blood-alcohol level was at least .08 percent.
An investigation into the fatal crash is continuing.